The relative rate constants for the reactions of hydrogen atoms with Fe(II), Cu(II) and methanol, have been obtained over a range of pH. Fe(II) reacts entirely as Fe(OH)2+ and there is no measurable contribution from Fe3+ even in 0.2 N perchloric acid. The ratio of rate constants are: MeOH : FeOH2+ : Cu2+ : : 1 : 480 : 38, and kFeOH2+![[double greater-than, compressed]](https://www.rsc.org/images/entities/char_2aa2.gif)
500 kFe3+.
J. H. Baxendale, R. S. Dixon and D. A. Stott, Trans. Faraday Soc., 1968, 64, 2398 DOI: 10.1039/TF9686402398
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