The apparent molar volumes of NaCl, KCl, KBr, KI, and n-Bu4NBr in the concentration range 0.001–1.0 M and at 25°C have been determined using a magnetically-operated dilatometer. The theoretical Debye-Hückel apparent molar volume limiting slope for 1–1 electrolytes at 25°C is satisfactorily approached by each electrolyte in the very dilute solution region.
L. A. Dunn, Trans. Faraday Soc., 1968, 64, 1898 DOI: 10.1039/TF9686401898
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