SCHEDULED MAINTENANCE
Elimination of carbon monoxide from acid chlorides by the Friedel-Crafts reaction is precluded if the resulting carbonium ions are restricted to non-planar geometry by bicyclic or other structures with a rigid molecular framework. In such cases the normal ketones are obtained.
D. G. Pratt and E. Rothstein, J. Chem. Soc. C, 1968, 2548 DOI: 10.1039/J39680002548
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