Reaction of 1-alkylcyclohexenes with zinc chloride–acetic anhydride produces 6-acetyl-1-alkylcyclohexenes in good yields, together with small amounts of the isomeric 1-acetyl-2-alkylidenecyclohexanes. Hydrogenation of of the unstaurated ketones readily affords 1-acetyl-2-alkylcyclohexanes.
J. K. Groves and N. Jones, J. Chem. Soc. C, 1968, 2215 DOI: 10.1039/J39680002215
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