The reaction of the enamines of 4-alkylcyclohexanones with acraldehyde, of cinnamaldehyde with 1-morpholinocyclohexene, and a stereospecific synthesis of cis-3-methylcyclo-octanol are described. The reaction of a cyclohex-3-enyl halide with a Grignard reagent is shown to lead to axial products. An explanation is proposed for the steric course of certain Michael additions.
R. A. Appleton, K. H. Baggaley, S. C. Egan, J. M. Davies, S. H. Graham and D. O. Lewis, J. Chem. Soc. C, 1968, 2032 DOI: 10.1039/J39680002032
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