The o.r.d. curves of some D-homo-steroids have been measured. Accepting the conformations proposed for these lactones from previous i.r. and n.m.r. evidence, the Cotton effects can be rationalised in terms of the sector rule.
W. Klyne, P. M. Scopes, R. C. Sheppard and S. Turner, J. Chem. Soc. C, 1968, 1954 DOI: 10.1039/J39680001954
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