Dehydration of 7 β-hydroxyhopane and of the 21 α-H epimer gives a series of 9(8 → 7)abeo-hopenes, as a result of a Wagner-Meerwein rearrangement. Dehydration of 7 α-hydroxyhopane and of the 21 α-H epimer is accompanied by migration of the C-8 methyl group.
R. E. Corbett, R. A. J. Smith and H. Young, J. Chem. Soc. C, 1968, 1823 DOI: 10.1039/J39680001823
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