Issue 0, 1968

Oxidative cyclisations of o-substituted anilines and benzoic acids with manganese dioxide

Abstract

In a neutral medium, oxidation by manganese dioxide of N-o-aminophenyl-, N-o-aminobenzyl-, and N-o-carboxyphenyl-amines gave benzimidazoles, quinazolones, and benzoxazinones, respectively. Similarly, o-alkylbenzoic acids yielded phthalides. Reaction mechanisms and spectral data of various products are discussed.

Article information

Article type
Paper

J. Chem. Soc. C, 1968, 1722-1726

Oxidative cyclisations of o-substituted anilines and benzoic acids with manganese dioxide

O. Meth-Cohn, H. Suschitzky and M. E. Sutton, J. Chem. Soc. C, 1968, 1722 DOI: 10.1039/J39680001722

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