The reactions between hexafluorobenzene and a series of diaroyl peroxides have been shown to give 2,3,4,5,6-pentafluorobiphenyl and appropriately substituted derivatives. The significance of the yields of the biaryls obtained and the nature of the other reaction products are discussed, and a mechanism for the reaction is suggested tentatively.
P. A. Claret, G. H. Williams and J. Coulson, J. Chem. Soc. C, 1968, 341 DOI: 10.1039/J39680000341
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