SCHEDULED MAINTENANCE
The kinetics of the acid catalysed decomposition of a number of diazo-ketones have been studied in perchloric, sulphuric, hydrochloric, and hydrobromic acids in either water or aqueous dioxan as solvent. The effect of added salts on the perchloric acid catalysed reaction has been investigated. Both the water and the halide ion reactions are shown to proceed by an A2 mechanism.
S. Aziz and J. G. Tillett, J. Chem. Soc. B, 1968, 1302 DOI: 10.1039/J29680001302
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...