SCHEDULED MAINTENANCE
The ultraviolet spectra of a series of cyclic multisulphur compounds have been measured. Long-wavelength absorptions of these compounds are interpreted in terms of d-orbital interactions between non-bonded sulphur atoms. Spiro-conjugation is invoked to interpret the anomalous spectrum of 1,5,7,11-tetrathiaspiro[5,5]undecane.
D. R. Williams, D. L. Coffen, P. E. Garrett and R. N. Schwartz, J. Chem. Soc. B, 1968, 1132 DOI: 10.1039/J29680001132
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