Issue 0, 1968
From the journal:

Journal of the Chemical Society B: Physical Organic

The reaction of O(23P) atoms with 1,1-difluoro-olefins

R. C. Mitchell  and  J. P. Simons  

Abstract

The occurrence of the elementary reaction O(23P)+ C2F4→ CF2O + CF2 has been verified through flash photolysis of NO2–C2F4 mixtures. A new class of reaction of the type O(23P)+ CF2= CXY [graphic omitted] has been discovered; when X, Y = halogen, the biradical intermediate leading to step (b) is formed preferentially. The transient production of the halogenocarbene CXY has been inferred from the results of photolysis in the presence of oxygen.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/J29680001005
Article type
Paper

J. Chem. Soc. B, 1968, 1005-1007

Permissions

Request permissions

The reaction of O(23P) atoms with 1,1-difluoro-olefins

R. C. Mitchell and J. P. Simons, J. Chem. Soc. B, 1968, 1005 DOI: 10.1039/J29680001005

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements