SCHEDULED MAINTENANCE
The rates of reaction of sulphuryl chloride with a number of derivatives of m-dimethoxybenzene in chlorobenzene show good correlation with the Hammett equation. The high value of the reaction constant (ρ=–4·0) confirms the heterolytic nature of the rate-determining step; further evidence of this mechanism is presented. Details are given for the preparation of pure derivatives of m-dimethoxybenzene.
R. Bolton, J. Chem. Soc. B, 1968, 712 DOI: 10.1039/J29680000712
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