The enthalpies and entropies of activation of the acid-catalysed hydrolysis of a series of cyclic acetals [graphic omitted], where n= 5, 6, 7, or 8, in dilute aqueous solution have been determined. The results are discussed in terms of the conformational requirements of the transition state.
P. Watts, J. Chem. Soc. B, 1968, 543 DOI: 10.1039/J29680000543
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