SCHEDULED MAINTENANCE
Ratios of rates of thallium(III) oxidation of substituted tris-(1,10-phenanthroline)iron(II) complexes have been determined. The logarithms of these ratios correlate linearly with the redox potentials of the iron(II)–iron(III) complex couples, a correlation which is consistent with an outer-sphere mechanism for these oxidations.
J. Burgess, J. Chem. Soc. A, 1968, 3123 DOI: 10.1039/J19680003123
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