The preparation of eleven heteropolytungstate anions, X2ZW17O62H2x–(X = P or As; Z = Mn, Co, Ni, or Zn) is described. These include the first heteropolyanions with MnIII as heteroatom. The stabilities of the anions towards acid and base, and the redox potentials and magnetic moments of the Z heteroatoms are reported, and the formulation of the anions and their spectra are discussed.
S. A. Malik and T. J. R. Weakley, J. Chem. Soc. A, 1968, 2647 DOI: 10.1039/J19680002647
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