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Issue 0, 1968
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Nuclear magnetic resonance studies of mixed dihalogenosilanes and related species

Abstract

Exchange between dihalogenosilanes and hydrogen halides leads to the formation of mixed dihalogenosilanes; 1H chemical shifts and 29SiH coupling constants have been obtained, and equilibrium constants measured for the reactions SiH2X2+ SiH2Y2 2SiH2XY. The usual additivity relationships are not well obeyed by the n.m.r. parameters in these systems. Evidence is presented for the existence of the species XSiH2CN (X = Cl, Br, I). The Raman spectrum of SiH2ICI has also been obtained.

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Article type: Paper
DOI: 10.1039/J19680002294
J. Chem. Soc. A, 1968, 2294-2297

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    Nuclear magnetic resonance studies of mixed dihalogenosilanes and related species

    E. A. V. Ebsworth, A. G. Lee and G. M. Sheldrick, J. Chem. Soc. A, 1968, 2294
    DOI: 10.1039/J19680002294

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