SCHEDULED MAINTENANCE
The complexes trans-PtHL(PEt3)2, where L is an o-, m-, or p- substituted benzoato-ligand or a substituted acetato-ligand, have been prepared and their 1H n.m.r. spectra have been determined. Linear correlations are found between the chemical shift of the hydrido-ligand, the platinum–hydrogen coupling constant, the platinum–hydrogen stretching frequency, and the pKa of the parent carboxylic acid. These are discussed.
P. W. Atkins, J. C. Green and M. L. H. Green, J. Chem. Soc. A, 1968, 2275 DOI: 10.1039/J19680002275
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