The compound WOCl3Br, prepared by reaction of bromine gas with potassium tri-µ-chloro-hexachloroditungstate(III), K3W2Cl9, has been characterized. It was one of a mixture of products which were separated by fractional sublimation. Small deviations in the stoicheiometry were consistent with the formula WOClnBr4-n, and the compounds were isostructural with WOCl4 and WOBr4. X-Ray data and far-i.r. spectra are reported.
P. M. Boorman, N. N. Greenwood and H. J. Whitfield, J. Chem. Soc. A, 1968, 2256 DOI: 10.1039/J19680002256
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