Issue 0, 1968

Vibrational spectra of halogen-bridged systems. Part II. Au2Cl6, Al2Br6, Al2I6, and In2I6

Abstract

Infrared and partial Raman data are reported and assigned for the title compounds. A normal-co-ordinate analysis has been made for auric chloride. The most significant result of the calculation is that the bridge bond stretching force constant in auric chloride is 73% that of the terminal bond, whereas it is approximately 50% in aluminium chloride; this difference is rationalised and generalised.

Article information

Article type
Paper

J. Chem. Soc. A, 1968, 2141-2144

Vibrational spectra of halogen-bridged systems. Part II. Au2Cl6, Al2Br6, Al2I6, and In2I6

D. M. Adams and R. G. Churchill, J. Chem. Soc. A, 1968, 2141 DOI: 10.1039/J19680002141

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