Issue 0, 1968
From the journal:

Journal of the Chemical Society A: Inorganic, Physical, Theoretical


The oxidation of bis(bipyridyl)copper(I) ions by oxygen and by hydrogen peroxide

I. Pecht  and  M. Anbar  

Abstract

The kinetics of the reactions of CuI(bipyridyl)2 with oxygen and hydrogen peroxide have been investigated using the stopped-flow technique. Both reactions are first-order in the copper(I) complex and in the oxidants. The specific rate constants measured are 6·5 × 103 and 8·5 × 102M–1 sec.–1 respectively. Hydrogen peroxide which is formed as an intermediate in the reduction of oxygen was shown, using oxygen-18 as tracer, to be formed without any incorporation of water oxygen.

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Article information

DOI
https://doi.org/10.1039/J19680001902
Article type
Paper

J. Chem. Soc. A, 1968, 1902-1904

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The oxidation of bis(bipyridyl)copper(I) ions by oxygen and by hydrogen peroxide

I. Pecht and M. Anbar, J. Chem. Soc. A, 1968, 1902 DOI: 10.1039/J19680001902

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