The detailed infrared, Raman, and electronic spectra of the polymeric chromium(III) alkoxides have been measured. In conjunction with studies of magnetic susceptibilities and X-ray powder photographs, it is concluded that the methoxide and ethoxide possess layer lattices with the chromium atoms in an octahedral environment. Application of a Urey–Bradley force field to CrIII(OMe)3 gives excellent agreement with observed infrared and Raman frequencies.
D. A. Brown, D. Cunningham and W. K. Glass, J. Chem. Soc. A, 1968, 1563 DOI: 10.1039/J19680001563
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