The stoicheiometry of the acid-catalysed aquation of the trisoxalatocobaltate(III) anion is represented by 10H++ 2Co(C2O4)33–⇌ 2Co2++ 5H2C2O4+ 2CO2. The rate of aquation is repressed by addition of oxalate ions and therefore a reversible dissociation yielding oxalate ions precedes the electron-transfer step.
J. Aggett and A. L. Odell, J. Chem. Soc. A, 1968, 1415 DOI: 10.1039/J19680001415
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