The infrared spectrum of [π-C5H5Fe(CO2)2] is markedly solvent dependent in the 500–700, 1700–2100, and 3500–4000 cm.–1 regions. The spectra can best be explained on the assumption that there are two bridged and one non-bridged isomer present in solutions, and that their proportions vary from solvent to solvent. These suggestions also account for the dipole moment of the compound.
A. R. Manning, J. Chem. Soc. A, 1968, 1319 DOI: 10.1039/J19680001319
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