Issue 0, 1968

Aquation of tris-[1,10-phenanthroline]iron(II) complexes in t-butyl alcohol–water mixtures

Abstract

Rates of acid aquation of several substituted tris-(1,10-phenanthroline)iron(II) complexes have been determined in aqueous t-butyl alcohol. Variation of rate constant with solvent composition and with nature of the ligand substituent and of the anion has been investigated. Activation parameters for aquation of the 5-nitro-complex have been obtained over a range of aqueous t-butyl alcohol solvent compositions. Results are discussed in terms of the effect of t-butyl alcohol on the structure of the water in aqueous t-butyl alcohol, and the consequent effects on rates and mechanism of aquation.

Article information

Article type
Paper

J. Chem. Soc. A, 1968, 1085-1088

Aquation of tris-[1,10-phenanthroline]iron(II) complexes in t-butyl alcohol–water mixtures

J. Burgess, J. Chem. Soc. A, 1968, 1085 DOI: 10.1039/J19680001085

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