Issue 0, 1968
From the journal:

Journal of the Chemical Society A: Inorganic, Physical, Theoretical


Some transition-metal acetylides

M. I. Bruce,   D. A. Harbourne,   F. Waugh  and  F. G. A. Stone  

Abstract

Treatment of bis(triethylphosphine)nickel dichloride with trifluoropropynylmagnesium iodide affords trans-(Et3P)2Ni(C[triple bond, length half m-dash]C·CF3)l. Similarly, from the halides trans-(Et3P)2MCl2(M = Pd or Pt) and (π-C5H5)2TiCl2 the trifluoropropynyl complexes trans-(Et3P)2M(C[triple bond, length half m-dash]C·CF3)2 and (π-C5H5)2 Ti(C[triple bond, length half m-dash]C·CF3)2, respectively, are obtained. Reaction between dicarbonyl-π-cyclopentadienyliron halides and the appropriate lithium acetylides yields the compounds π-C5H5Fe(CO)2C[triple bond, length half m-dash]CR (R = CF3, C6F5, or C6H5). Evidence for the formation of the two complexes RC[triple bond, length half m-dash]CRe(CO)5(R = C6F5 or C6H5) has been obtained.

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Article information

DOI
https://doi.org/10.1039/J19680000356
Article type
Paper

J. Chem. Soc. A, 1968, 356-359

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Some transition-metal acetylides

M. I. Bruce, D. A. Harbourne, F. Waugh and F. G. A. Stone, J. Chem. Soc. A, 1968, 356 DOI: 10.1039/J19680000356

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