SCHEDULED MAINTENANCE
[Rh2Cl2(CO)4] and [Rh2Cl2(C2H4)4] react in benzene solution to give [Rh2Cl2(CO)2(C2H4)2] in good yield. [Rh2Cl2(CO)2(C2H4)2] reacts with hydrogen chloride to given an ethylrhodium(III) complex [RhCl2Et(CO)]x which in turn reacts with dimethylphenylphosphine to give [RhCl2Et(CO)(PMe2Ph)2]. Nuclear magnetic resonance and infrared data are given.
J. Powell and B. L. Shaw, J. Chem. Soc. A, 1968, 211 DOI: 10.1039/J19680000211
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