Gas-phase reactions between carbon monoxide, chlorine and nitrogen dioxide
Abstract
The reactions between carbon monoxide, chlorine and nitrogen dioxide have been studied over the temperature range 381–473°C by manometric and photometric methods. The kinetic equations for this system has been established, and the proposed mechanism leads to a velocity constant for the reaction, COCl + NO2→CO2+NO + Cl of k= 108.84 exp (+160±250/RT)l. mole–1 sec–1.