Volume 63, 1967

Chemical overshoot during shock pyrolysis of organic molecules

Abstract

C2 Swan band emission measurements for methane and ethylene shock pyrolysis show similar features to those reported for acetone.1 Equilibrium emissivity measurements for all three molecules are in good agreement with computer calculations of C2 concentrations. For richer mixtures the endothermic fragmentation immediately behind the shock front is followed by exothermic recombination to achieve chemical equilibrium.

Article information

Article type
Paper

Trans. Faraday Soc., 1967,63, 2190-2195

Chemical overshoot during shock pyrolysis of organic molecules

B. P. Levitt, A. Parsons and N. Wright, Trans. Faraday Soc., 1967, 63, 2190 DOI: 10.1039/TF9676302190

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