Thermochemistry of the trialkylthioboranes and triphenylthioborane
Abstract
Values for the standard enthalpies of formation and transition (condensed phase to gas) are reported for the series (RS)3B, where R CH3, n-C3H7, n-C4H9, n-C5H11 and C6H5. The energy of the boron-sulphur bond in these compounds is evaluated and is found to be nearly constant except for trimethylthioborane.