SCHEDULED MAINTENANCE
The gas-phase dehydrobromination of 3-bromopentane has been shown to be a homogeneous first-order reaction, unaffected by the presence of cyclohexene. The rate constants follow the Arrhenius equation k1= 1013 · 51 exp(–45,440/RT). These observations are consistent with a molecular mechanism but not with the chain mechanism for bromide pryolysis proposed by Wojciechowski and Laidler.
N. Capon, A. Maccoll and R. A. Ross, Trans. Faraday Soc., 1967, 63, 1152 DOI: 10.1039/TF9676301152
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