Solutions containing K3Fe(CN)6+K4Fe(CN)6+HCOONa have been X-irradiated to measure radical and molecular product yields over the pH range 10–13.5. GH2 and Geq–+GH are constant over this range of pH. There are indications that the precisely known decrease in GH2O2 which occurs when the pH is increased is matched by an appropriate (= 2ΔGH2O2) increase in GOH.
C. E. Burchill, F. S. Dainton and D. Smithies, Trans. Faraday Soc., 1967, 63, 932 DOI: 10.1039/TF9676300932
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