Volume 63, 1967

Enthalpy of formation of oxalyl chloride and the COCl radical

Abstract

The heat of formation for liquid oxalyl chloride has been determined by reaction calorimetry to be –85.6 ± 0.5 kcal/mole. From this it is deduced that ΔH°f298 oxalyl chloride (g)=– 78.0 ± 1.4 kcal/mole and ΔH°f298(COCl,g)=–4.0 ± 3 kcal/mole.

Article information

Article type
Paper

Trans. Faraday Soc., 1967,63, 879-882

Enthalpy of formation of oxalyl chloride and the COCl radical

L. C. Walker and H. Prophet, Trans. Faraday Soc., 1967, 63, 879 DOI: 10.1039/TF9676300879

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