SCHEDULED MAINTENANCE:
Compared with the corresponding reactions of 3-oxo-Δ4-steroids, hydrogenation and alkaline epoxidation of 4-methylcholestenone and 4-methyltestosterone give higher proportions of 5α-products. α-Epoxides were obtained from reactions of cholestenone and 4-methylcholestenone with peroxylauric acid.
H. B. Henbest, W. R. Jackson and I. Malunowicz, J. Chem. Soc. C, 1967, 2469 DOI: 10.1039/J39670002469
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