The general applicability of the reactions of imino- and methylene-phosphoranes with dimethyl acetylenedicarboxylate has been studied, and the properties of the adducts have been investigated. Methylenehydrazono-phosphoranes react with the acetylene as substituted iminophosphoranes, and not as 1,4-dipolar species.
G. W. Brown, J. Chem. Soc. C, 1967, 2018 DOI: 10.1039/J39670002018
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