SCHEDULED MAINTENANCE
Equilibration of cis- and trans-5-t-butylcyclohex-2-enol indicates that, in aqueous solvents, the allylic hydroxy-group favours the quasi-equatorial orientation by 0·4 kcal./mole. The acetoxy- and methoxy-groups of the derived acetates and methyl ethers (studied in acetic acid and methanol, respectively) show no significant orientational preference.
R. J. Ferrier and N. Prasad, J. Chem. Soc. C, 1967, 1417 DOI: 10.1039/J39670001417
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