Issue 0, 1967

Asymmetric syntheses. Part IV. The stereochemistry of the reduction of cyclohexanones

Abstract

Reduction of 3,3,5-trimethylcyclohexanone with cyclic complexes of lithium aluminium hydride are described. The axial–equatorial ratio of the cyclohexanols obtained from these and other reductions are interpreted by postulating participation of the flexible form of the ketone in the reaction.

Article information

Article type
Paper

J. Chem. Soc. C, 1967, 1159-1163

Asymmetric syntheses. Part IV. The stereochemistry of the reduction of cyclohexanones

S. R. Landor and J. P. Regan, J. Chem. Soc. C, 1967, 1159 DOI: 10.1039/J39670001159

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