Issue 0, 1967

The reaction of benzoyl isothiocyanate with hydrazine derivatives. Part II. Reaction with some alkyl hydrazones

Abstract

The reaction of benzoyl isothiocyanate with 1-alkyl-2-isopropylidenehydrazines leads to the formation of 1,3,4,6-oxatriazepine-5-thione derivatives rather than the open-chain benzoyl thiosemicarbazones

PhCO·NH·CS·NR·N:CMe2. The related benzylidenehydrazines gave non-cyclic products under comparable conditions. Structural assignments have been made largely on the basis of spectral data. Acid hydrolysis of the oxatriazepinethiones to 1,2,4-triazoline-5-thiones has also been studied.

Article information

Article type
Paper

J. Chem. Soc. C, 1967, 952-956

The reaction of benzoyl isothiocyanate with hydrazine derivatives. Part II. Reaction with some alkyl hydrazones

G. J. Durant, J. Chem. Soc. C, 1967, 952 DOI: 10.1039/J39670000952

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