Issue 0, 1967

Cyclopropanones and related compounds. Part III. Addition of some isoelectronic molecules to olefins and dienes

Abstract

N-Ethylmethyleneaziridine adds to tetracyanoethylene to form a cyclobutane in which the two protons of the methylene of the N-ethyl group have become magnetically different. An unusual reaction takes place between the aziridine and dimethyl acetylenedicarboxylate, producing trimethyl 1-ethylpyrrole-2,3,4-tricarboxylate. Feist's ester gives normal Diels–Alder adducts with furan and cyclopentadiene, but with the less reactive anthracene rearrangement occurs first.

Article information

Article type
Paper

J. Chem. Soc. C, 1967, 928-931

Cyclopropanones and related compounds. Part III. Addition of some isoelectronic molecules to olefins and dienes

R. C. Cookson, B. Halton, I. D. R. Stevens and C. T. Watts, J. Chem. Soc. C, 1967, 928 DOI: 10.1039/J39670000928

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