2- and 4-Alkylpyridines, when heated under reflux with phenylsodium in benzene solution, give highly coloured sodio-derivatives of the bases, which on treatment with alkyl halides yield higher alkylpyridines without isomerisation.
R. Grzeskowiak, G. H. Jeffery and A. Watling, J. Chem. Soc. C, 1967, 326 DOI: 10.1039/J39670000326
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