SCHEDULED MAINTENANCE:
Cyclic sulphites react with chlorine to give chloroalkyl chlorosulphates [e.g., Cl·CH2·CH2·O·SO2Cl] in almost quantitative yield. the corresponding bromination of ethylene sulphite leads to a mixture of products including 2-bromoethyl bromoacetate and 2-bromoethanol.
P. A. Bristow, R. G. Jones and J. G. Tillett, J. Chem. Soc. C, 1967, 314 DOI: 10.1039/J39670000314
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