The equilibrium constant K=[OEt–][H2O]/[OH–][EtOH] has been calculated for mixtures of water and ethanol containing up to 35% by volume of ethanol by measuring the simultaneous rates of hydrolysis and ethanolysis of various solutes. The values of K vary as the solvent composition is changed, and also from one solute to another.
J. R. Aspland, A. Johsnon and R. H. Peters, J. Chem. Soc. B, 1967, 1041 DOI: 10.1039/J29670001041
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