The localised-orbital model for the determination of the effects of substituents on π-electron systems is extended to allow for an additional component to the Iπ effect. It is then used to correlate successfully substituent effects on various molecular properties of benzene and substituted benzenes.
M. Godfrey, J. Chem. Soc. B, 1967, 799 DOI: 10.1039/J29670000799
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