Nuclear magnetic resonance measurements have been made of equilibria involving addition of water, sodium hydrogen sulphite, and substituted alcohols to aldehydes and ketones. The accuracy compares favourably with that of spectrophotometric measurements. The variation in degree of reaction is discussed in terms of known electronic and steric effects.
D. L. Hooper, J. Chem. Soc. B, 1967, 169 DOI: 10.1039/J29670000169
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