A theoretical interpretation is given of substituent effects on J(13C–H) in methane and J(29Si–H) in silane. The extended Hückel theory of Pople and Santry is used. The important parameter is the electronegativity of the substituent, introduced via the Coulomb integral.
R. Ditchfield, M. A. Jensen and J. N. Murrell, J. Chem. Soc. A, 1967, 1674 DOI: 10.1039/J19670001674
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