Issue 0, 1967
From the journal:

Journal of the Chemical Society A: Inorganic, Physical, Theoretical


Cobalt(II) and nickel(II) bisdiarsine diperchlorates and dinitrates

G. A. Rodley  and  P. W. Smith  

Abstract

The infrared data for the oxyanions in trans-MD2(ClO4)2 and MD2(NO3)2(M = Co and Ni) are presented and interpreted in terms of association of the anions with the metal ions. The bonding is stronger in the cobalt (d7) complexes than in the corresponding nickel (d8) complexes. The complex trans-CoD2(ClO4)2 exists in two crystalline modifications. Infrared and X-ray data suggest that the association of perchlorate ions is essentially covalent in one form and ionic in the other.

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Article information

DOI
https://doi.org/10.1039/J19670001580
Article type
Paper

J. Chem. Soc. A, 1967, 1580-1583

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Cobalt(II) and nickel(II) bisdiarsine diperchlorates and dinitrates

G. A. Rodley and P. W. Smith, J. Chem. Soc. A, 1967, 1580 DOI: 10.1039/J19670001580

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