Issue 0, 1967
From the journal:

Journal of the Chemical Society A: Inorganic, Physical, Theoretical


A convenient and efficient preparation of trifluoromethyl-phosphorus and -arsenic hydrides

R. G. Cavell  and  R. C. Dobbie  

Abstract

The compounds CF3MH2 and (CF3)2MH (M = P or As) can be prepared in high yield by the reduction of the corresponding iodides with hydrogen iodide and mercury. Under the same conditions the diphosphine and diarsine, (CF3)2M·M(CF3)2, can be reduced to (CF3)2MH, and the cyclic tetramer and pentamer, (CF3M)4,5 to CF3MH2.

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Article information

DOI
https://doi.org/10.1039/J19670001308
Article type
Paper

J. Chem. Soc. A, 1967, 1308-1310

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A convenient and efficient preparation of trifluoromethyl-phosphorus and -arsenic hydrides

R. G. Cavell and R. C. Dobbie, J. Chem. Soc. A, 1967, 1308 DOI: 10.1039/J19670001308

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