Equilibrium constants have been determined both by pH titration and spectrophotometric methods for the stepwise formation at 25° of Pd(OH)2(aq) from Pd2+(aq) and OH–(aq). A standard electrode potential has been measured for the reaction Pd = Pd2++ 2e–. Possible formation of polynuclear species is considered and discussed.
R. M. Izatt, D. Eatough and J. J. Christensen, J. Chem. Soc. A, 1967, 1301 DOI: 10.1039/J19670001301
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