Issue 0, 1967
From the journal:

Journal of the Chemical Society A: Inorganic, Physical, Theoretical


Heterocyclic chelating agents. Part I. Metal complexes of 4-2′-pyridylimidazole

W. J. Eilbeck,   F. Holmes,   G. G. Phillips  and  A. E. Underhill  

Abstract

A study has been made of the metal complexes of 4-2′-pyridylimidazole (A) in aqueous solution at 25·0° and ionic background 0·1M in nitrate ions. The acid dissociation constants of the protonated ligand species H2A2+ and HA+ have been measured. Formation curves have been obtained and accurate formation constants for the complexes MA2+, MA22+, and MA32+(where M = Fe, Co, Ni, Cu, and Zn) have been calculated by a least-squares method on a high-speed digital computer. The results are discussed in relation to metal–ligand π-bonding.

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Article information

DOI
https://doi.org/10.1039/J19670001161
Article type
Paper

J. Chem. Soc. A, 1967, 1161-1166

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Heterocyclic chelating agents. Part I. Metal complexes of 4-2′-pyridylimidazole

W. J. Eilbeck, F. Holmes, G. G. Phillips and A. E. Underhill, J. Chem. Soc. A, 1967, 1161 DOI: 10.1039/J19670001161

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