The intensity of the mixed-valence absorption in a series of mixed-valence chlorocuprates has been measured as a function of the mole fraction of copper(I). The low intensity of the band agrees with its assignment as an intermolecular charge transfer from a chlorocuprate(I) anion to a chlorocuprate(II).
P. Day and D. W. Smith, J. Chem. Soc. A, 1967, 1045 DOI: 10.1039/J19670001045
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